I"ve had a scan through several different manufacturer MSDS, and apart from the standard, health warnings about contact and sniffing the stuff, they seem to vary a bit in their extra info, One states it should not be exposed to temps >50c which would mean that if the expanda foam is ' naked" (not covered by several layers of grout/render etc) then exposing it to temps above 50c (EG heat emitter) could produce highly toxic fumes/or catch fire. one of the MSDS commented on not suitable for aquariums, so if anyone is thinking of using expandafoam for aquariums or frog tanks then please reconsider !, if you are using it to shape a unique water bowl for your reptiles then I would recommend triple/quadruple sealing it with an appropriate sealer.
Like most things, common sense should be your guide. If something smells 'chemical' then theres a good chance it has a 'flash point' (a temp that it will ignite without direct flame)
common sense should also tell you that being a plastic type of substance, both the expanda foam and the normal styrofoam will melt if they get too hot and heat sources placed accordingly. and above all if in doubt look for a better alternative and above all STAY SAFE ! !
its all looking good so far Mel, how many more coats of render/liquid sandstone have you got to put on (I can see white spots in one of the last photos)